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diisopropyl azodicarboxylate
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Diisopropyl azodicarboxylate (DIAD) is the diisopropyl ester of azodicarboxylic acid. It is used as a reagent in the production of many organic compounds. It is often used in the Mitsunobu reaction〔
〕 where it serves as an oxidizer of triphenylphosphine to triphenylphosphine oxide. It has also been used to generate aza-Baylis-Hillman adducts with acrylates.〔
〕 It can also serve as a selective deprotectant of N-benzyl groups in the presence of other protecting groups.〔
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It is sometimes preferred to diethyl azodicarboxylate (DEAD) because it is more hindered, and thus less likely to form hydrazide byproducts.
==References==
抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』
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